Beilstein J. Org. Chem.2013,9, 1346–1351, doi:10.3762/bjoc.9.152
]. The Ullmanreaction is often used to prepare diaryl ethers, but this reaction has the disadvantages of high reaction temperatures and intolerance to a wide variety of functional groups, with the major weakness being the inconsistency in the products obtained by the use of different copper sources [22
Beilstein J. Org. Chem.2009,5, No. 51, doi:10.3762/bjoc.5.51
, differential scanning calorimetry and X-ray diffraction. In addition its lamellar crystal structure, electrochemical behaviour and UV (absorption and emission) properties are reported.
Keywords: imidazolium; ionic liquid crystals; Ullmanreaction; Introduction
Over the past decade extensive studies of ionic